That’s a lot of ships Syd! But I’ll do it for you~

Giovanni/Archer (SubordinateShipping – These two probably had the best relationship out of all the boss/subordinate ships. They were just fwb even if Archer had romantic feelings, but they respected each other and remain on good terms.)

Giovanni/Ariana (SilverSpawnShipping – The only reason this is so high up is because they were married. It was not a healthy relationship though and it was a very bitter and spiteful marriage overall.)

Lysandre/Bryony (RiskShipping – They were not romantically involved and only hooked up a few times, but Lysandre never treated Bryony poorly and had he not died, he would have supported her and their son.)

Archie/Shelly (ShiverMeTimbersShipping – They probably could have dated under different circumstances, being close childhood friends.)

Guzma/Plumeria (SkullShipping – Same with Archie and Shelly, the could have easily dated under different circumstances.)

Archie/Matt (SailorShipping – Less likely than Archie/Shelly, but perhaps could have happened.)
   
Cyrus/Jupiter (TBHShipping – They do hook up but it’s just Cyrus indulging Jupiter hence why it’s not higher on the list.) 

Cyrus/Saturn (GingaShipping – Perhaps if Saturn had been bolder, he too could have taken the same opportunity Jupiter did.)

Maxie/Courtney (AuthorityShipping – Courtney had some feelings for her boss, but never confessed them, nor did she ever expect Maxie to return them.)
   
Lysandre/Aliana (TriumphShipping – If Aliana had wanted to, they could have hooked up probably, but there weren’t any romantic feelings.)

Lysandre/Celosia (SuccessShipping – Same deal as with Aliana.)

Giovanni/Petrel (MusicalTheaterShipping – Same deal as with the above two.)

Giovanni/Mable (RedMapleShipping – Lysandre wasn’t really Mable’s type hence why she’s lower down on the list.)

Cyrus/Mars (BetelgeuseShipping – Mars only had a celebrity crush on Cyrus and never seriously considered her feelings to be real. She admires him, but that’s about it.)

Giovanni/Proton (DarkDesireShipping – Proton may have found his boss attractive, but he knew his brother Archer was the boss’ favorite so he wouldn’t interfere. He also would have been a teenager any time a relationship between him and Giovanni could have happened and Giovanni isn’t about that.)

Maxie/Tabitha (LeadershipShipping – I don’t headcanon Tabitha to have any romantic feelings for Maxie so…)

Lusamine/Wicke (HeavenlyShipping – Lusamine is too focused on finding her husband to bother with outside relationship.)

Lusamine/Faba (No Ship Name – Same as above.)

Lysandre/Xerosic (DoomsdayShipping – No attraction here, Xerosic has no interest in relationships while he’s focusing on getting back home.)

Cyrus/Charon (GlobalShipping – No attraction here either.)

Ghetsis/Literally Anyone (I headcanon him as ace/aro so he’s the least likely of anyone to end up in a relationship.)